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  7. Zirconium(IV) chloride, 98%, cont. 1-2% hafnium(IV) chloride, Thermo Scientific Chemicals

Zirconium(IV) chloride, 98%, cont. 1-2% hafnium(IV) chloride, Thermo Scientific Chemicals

21.70€ - 65.00€

Identificatori chimici

CAS 10026-11-6
Formula molecolare ZrCl4
Numero MDL MFCD00011306
Sinonimo Zirconium tetrachloride
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Produkte 2
Produktcode Marke Quantità Preis Menge & Verfügbarkeit  
Produktcode Marke Quantità Preis Menge & Verfügbarkeit  
11373716
Sicherheitsdatenblatt (SDS) Unterlagen ansehen
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Thermo Scientific Alfa Aesar
L14891.18 		50 g N/A N/A N/A
11383716
Sicherheitsdatenblatt (SDS) Unterlagen ansehen
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Thermo Scientific Alfa Aesar
L14891.30 		250 g N/A N/A N/A
Beschreibung

Beschreibung

Zirconium(IV) chloride catalyzes the trans-hydrostannylation of acetylenes with Tri-n-butyl­tin hydride. It is used as a superior catalyst for the fries rearrangement of aryl acetates, giving the least hindered ortho-acetyl phenol in high yields at ambient temperatures. In the presence of ZrCl4, chloromethyl ethers are formed under mild conditions from acid chlorides and trioxane or paraformaldehyde.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Zirconium(IV) chloride catalyzes the trans-hydrostannylation of acetylenes with Tri-n-butyl­tin hydride. It is used as a superior catalyst for the fries rearrangement of aryl acetates, giving the least hindered ortho-acetyl phenol in high yields at ambient temperatures. In the presence of ZrCl4, chloromethyl ethers are formed under mild conditions from acid chlorides and trioxane or paraformaldehyde.

Solubility
Reacts with water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Handle and store under inert gas. It is sensitive to moisture. Incompatible with bases and oxidizing agents.
Spezifikation

Chemische Identifikatoren

10026-11-6
ZrCl4
MFCD00011306
Zirconium tetrachloride

Spezifikation

Zirconium(IV) chloride
10026-11-6
ZrCl4
UN2503
Zirconium tetrachloride
233.03
Moisture sensitive
331°C (sublimation)
cont. 1 to 2% hafnium(IV) chloride
MFCD00011306
14,10174
Reacts with water.
98%
2.803
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Sicherheit und Handhabung

Sicherheit und Handhabung

GHS H Statement
H314-H318-H302
Causes severe skin burns and eye damage.
Causes serious eye damage.
Harmful if swallowed.

P234-P264b-P270-P280-P284-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P310-P312-P330-P331-P363-P390-P501c

H290-H302-H314

missing translation for 'dotInformation' : Transport Hazard Class: 8; Packing Group: III; Proper Shipping Name: ZIRCONIUM TETRACHLORIDE

missing translation for 'einecsNumber' : 233-058-2

missing translation for 'rtecsNumber' : ZH7175000

missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures; Store under Argon

Sicherheitsdatenblatt (SDS)
Dokumentation

Dokumentation

Produktzertifizierungen

RUO – Research Use Only

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