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  7. (Trimethylsilyl)diazomethane, 2M in hexanes, Thermo Scientific Chemicals

(Trimethylsilyl)diazomethane, 2M in hexanes, Thermo Scientific Chemicals

Codice prodotto. 11322739
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Quantità:
5 mL
25 mL
100 mL
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Les retours ne sont pas autorisés pour ce produit. Consulta la politica di reso

Descrizione

CAS: 18107-18-1 | C4H10N2Si | 114.223 g/mol

(Trimethylsilyl)diazomethane is used as a methylating agent in organic chemistry. It is utilized in Gas Chromatography- Mass-Spectrometry (GC-MS) for the analysis of various carboxylic compounds. It is involved as a reagent in the Doyle-Kirmse reaction with allyl sulfides and allyl amines. It is considered and used as a less-explosive replacement fordiazomethane. It is also used as a reactant for Unnatural alfa-amino acid derivatives containing gem-bisphosphonates through Michael addition reaction, imidazolo[2,1-b]benzothiazole derivatives and aigialomycin D analogues.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(Trimethylsilyl)diazomethane is used as a methylating agent in organic chemistry. It is utilized in Gas Chromatography- Mass-Spectrometry (GC-MS) for the analysis of various carboxylic compounds. It is involved as a reagent in the Doyle-Kirmse reaction with allyl sulfides and allyl amines. It is considered and used as a less-explosive replacement fordiazomethane. It is also used as a reactant for Unnatural alfa-amino acid derivatives containing gem-bisphosphonates through Michael addition reaction, imidazolo[2,1-b]benzothiazole derivatives and aigialomycin D analogues.

Solubility
Immiscible with water. Miscible with organic solvents.

Notes
(Trimethylsilyl)diazomethane (TMSD) in alcoholic solvents under acidic or basic conditions can lead to the formation of diazomethane. TMSD is under review by the National Toxicological Program for potential inhalation hazards.Incompatible with oxidizing agents, chlorine, fluorine and perchlorates.

Identificatori chimici

CAS 18107-18-1
Formula molecolare C4H10N2Si
Molecular Weight (g/mol) 114.223
Numero MDL MFCD00053946
InChI Key ONDSBJMLAHVLMI-UHFFFAOYSA-N
Sinonimo trimethylsilyl diazomethane, trimethylsilyldiazomethane, diazomethyl trimethylsilane, tms-diazomethane, diazomethyl trimethyl silane, tmschn2, silane, diazomethyl trimethyl, unii-qi98hqo8c4, diazomethyl-trimethyl-silane, qi98hqo8c4
PubChem CID 167693
IUPAC Name diazomethyl(trimethyl)silane
SMILES C[Si](C)(C)C=[N+]=[N-]

Specifica

Materiale o nome chimico (Trimethylsilyl)diazomethane
Quantità 5 mL
Numero UN UN3383
Beilstein 1902903
Punto d'infiammabilità −23°C (−10°F)
Informazioni di solubilità Immiscible with water. Miscible with organic solvents.
Peso formulazione 114.22
Concentration or Composition (by Analyte or Components) 2M in hexanes
Sensibilità Light and moisture sensitive
Densità 0.718

RUO – Research Use Only

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