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Nitrosonium tetrafluoroborate, 98%, Thermo Scientific Chemicals

CAS: 14635-75-7 | BF4HNO2 | 133.82 g/mol

31.00€ - 325.00€

Identificatori chimici

CAS 14635-75-7
Formula molecolare BF4HNO2
Molecular Weight (g/mol) 133.82
Numero MDL MFCD00011433
InChI Key XYRQURYIJKJVSF-UHFFFAOYSA-N
Sinonimo nitrosonium tetrafluoroborate, nitrosyl tetrafluoroborate, nitrosyltetrafluoroborate, nobf4, nitrilooxonium tetrafluoroborate, azanylidyneoxidanium tetrafluoroborate
PubChem CID 11137142
IUPAC Name azanylidyneoxidanium;tetrafluoroborate
SMILES [O-][NH+]=O.F[B-](F)(F)F
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Prodotti 3
Codice del prodotto Marca Quantità Prezzo Quantità e disponibilità  
Codice del prodotto Marca Quantità Prezzo Quantità e disponibilità  
11468730
SDS Vedere i documenti
Thermo Scientific Alfa Aesar
A15806.04
2 g
31.00€
2g
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11472468
SDS Vedere i documenti
Thermo Scientific Alfa Aesar
A15806.09
10 g
99.30€
10g
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11482468
SDS Vedere i documenti
Thermo Scientific Alfa Aesar
A15806.18
50 g
325.00€
50g
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Descrizione

Descrizione

Nitrosonium tetrafluoroborate is a nitrosating agent and oxidizer used in organic synthesis. It is also used to convert arylamines directly to diazonium tetrafluoroborates, which undergo the Balz-Schiemann reaction in situ to give high yields of aryl fluorides. Further, it is used as a catalyst for iodination of aromatics by iodide ion with air as oxidant, conversion of secondary amines to nitrosamines and in deamination of primary amides. It is involved in the conversion of arylhydrazines to azides. In addition to this, it reacts with ferrocene to prepare ferrocenium tetrafluoroborate.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Nitrosonium tetrafluoroborate is a nitrosating agent and oxidizer used in organic synthesis. It is also used to convert arylamines directly to diazonium tetrafluoroborates, which undergo the Balz-Schiemann reaction in situ to give high yields of aryl fluorides. Further, it is used as a catalyst for iodination of aromatics by iodide ion with air as oxidant, conversion of secondary amines to nitrosamines and in deamination of primary amides. It is involved in the conversion of arylhydrazines to azides. In addition to this, it reacts with ferrocene to prepare ferrocenium tetrafluoroborate.

Solubility
Soluble in acetonitrile.

Notes
Hygroscopic. Air and moisture sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with acids and amines.
Specifica

Identificatori chimici

14635-75-7
133.82
XYRQURYIJKJVSF-UHFFFAOYSA-N
11137142
[O-][NH+]=O.F[B-](F)(F)F
BF4HNO2
MFCD00011433
nitrosonium tetrafluoroborate, nitrosyl tetrafluoroborate, nitrosyltetrafluoroborate, nobf4, nitrilooxonium tetrafluoroborate, azanylidyneoxidanium tetrafluoroborate
azanylidyneoxidanium;tetrafluoroborate

Specifica

250°C (0.01 mmHg)(Sublimation)
250°C (Sublimation)
BF4HNO2
UN3260
nitrosonium tetrafluoroborate, nitrosyl tetrafluoroborate, nitrosyltetrafluoroborate, nobf4, nitrilooxonium tetrafluoroborate, azanylidyneoxidanium tetrafluoroborate
XYRQURYIJKJVSF-UHFFFAOYSA-N
azanylidyneoxidanium;tetrafluoroborate
11137142
98%
Moisture sensitive
Nitrosonium tetrafluoroborate
14635-75-7
MFCD00011433
14,6649
Soluble in acetonitrile.
[O-][NH+]=O.F[B-](F)(F)F
133.82
116.82
Irritating
2.185
Videos
Safety and Handling

Safety and Handling

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.

P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

H314-H318

missing translation for 'dotInformation' : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.

missing translation for 'einecsNumber' : 238-679-2

missing translation for 'tsca' : Yes

Recommended Storage : Keep cold

Product Identifier
  • Nitrosonium tetrafluoroborate

Signal Word
  • Pericolo

Hazard Category
  • Lesione oculare grave/irritazione oculare Categoria 1
  • Corrosione/irritazione della pelle Categoria 1B

Hazard Statement
  • H314-Provoca gravi ustioni cutanee e gravi lesioni oculari.
  • H318-Provoca gravi lesioni oculari.
  • EUH031-A contatto con acidi libera gas tossici.

Precautionary Statement
  • P280-Indossare guanti/indumenti protettivi/Proteggere gli occhi/il viso.
  • P301+P330+P331-IN CASO DI INGESTIONE: sciacquare la bocca. NON provocare il vomito.
  • P305+P351+P338-IN CASO DI CONTATTO CON GLI OCCHI: sciacquare accuratamente per parecchi minuti. Togliere le eventuali lenti a contatto se è agevole farlo. Continuare a sciacquare.
  • P310-Contattare immediatamente un CENTRO ANTIVELENI/un medico .

Supplemental information
  • MIXTURE LIST-Contiene: Nitrosonium tetrafluoroborate

SDS
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RUO – Research Use Only

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