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Nitrosonium tetrafluoroborate, 98%, Thermo Scientific Chemicals
CAS: 14635-75-7 | BF4HNO2 | 133.82 g/mol
31.00€ - 325.00€
Identificatori chimici
CAS | 14635-75-7 |
---|---|
Formula molecolare | BF4HNO2 |
Molecular Weight (g/mol) | 133.82 |
Numero MDL | MFCD00011433 |
InChI Key | XYRQURYIJKJVSF-UHFFFAOYSA-N |
Sinonimo | nitrosonium tetrafluoroborate, nitrosyl tetrafluoroborate, nitrosyltetrafluoroborate, nobf4, nitrilooxonium tetrafluoroborate, azanylidyneoxidanium tetrafluoroborate |
PubChem CID | 11137142 |
IUPAC Name | azanylidyneoxidanium;tetrafluoroborate |
SMILES | [O-][NH+]=O.F[B-](F)(F)F |
Codice del prodotto | Marca | Quantità | Prezzo | Quantità e disponibilità | |||||
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Codice del prodotto | Marca | Quantità | Prezzo | Quantità e disponibilità | |||||
11468730
|
Thermo Scientific Alfa Aesar
A15806.04 |
2 g |
31.00€
2g |
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11472468
|
Thermo Scientific Alfa Aesar
A15806.09 |
10 g |
99.30€
10g |
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11482468
|
Thermo Scientific Alfa Aesar
A15806.18 |
50 g |
325.00€
50g |
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Descrizione
Nitrosonium tetrafluoroborate is a nitrosating agent and oxidizer used in organic synthesis. It is also used to convert arylamines directly to diazonium tetrafluoroborates, which undergo the Balz-Schiemann reaction in situ to give high yields of aryl fluorides. Further, it is used as a catalyst for iodination of aromatics by iodide ion with air as oxidant, conversion of secondary amines to nitrosamines and in deamination of primary amides. It is involved in the conversion of arylhydrazines to azides. In addition to this, it reacts with ferrocene to prepare ferrocenium tetrafluoroborate.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsNitrosonium tetrafluoroborate is a nitrosating agent and oxidizer used in organic synthesis. It is also used to convert arylamines directly to diazonium tetrafluoroborates, which undergo the Balz-Schiemann reaction in situ to give high yields of aryl fluorides. Further, it is used as a catalyst for iodination of aromatics by iodide ion with air as oxidant, conversion of secondary amines to nitrosamines and in deamination of primary amides. It is involved in the conversion of arylhydrazines to azides. In addition to this, it reacts with ferrocene to prepare ferrocenium tetrafluoroborate.
Solubility
Soluble in acetonitrile.
Notes
Hygroscopic. Air and moisture sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with acids and amines.
Identificatori chimici
14635-75-7 | |
133.82 | |
XYRQURYIJKJVSF-UHFFFAOYSA-N | |
11137142 | |
[O-][NH+]=O.F[B-](F)(F)F |
BF4HNO2 | |
MFCD00011433 | |
nitrosonium tetrafluoroborate, nitrosyl tetrafluoroborate, nitrosyltetrafluoroborate, nobf4, nitrilooxonium tetrafluoroborate, azanylidyneoxidanium tetrafluoroborate | |
azanylidyneoxidanium;tetrafluoroborate |
Specifica
250°C (0.01 mmHg)(Sublimation) | |
250°C (Sublimation) | |
BF4HNO2 | |
UN3260 | |
nitrosonium tetrafluoroborate, nitrosyl tetrafluoroborate, nitrosyltetrafluoroborate, nobf4, nitrilooxonium tetrafluoroborate, azanylidyneoxidanium tetrafluoroborate | |
XYRQURYIJKJVSF-UHFFFAOYSA-N | |
azanylidyneoxidanium;tetrafluoroborate | |
11137142 | |
98% | |
Moisture sensitive |
Nitrosonium tetrafluoroborate | |
14635-75-7 | |
MFCD00011433 | |
14,6649 | |
Soluble in acetonitrile. | |
[O-][NH+]=O.F[B-](F)(F)F | |
133.82 | |
116.82 | |
Irritating | |
2.185 |
Safety and Handling
GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.
P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
H314-H318
missing translation for 'dotInformation' : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
missing translation for 'einecsNumber' : 238-679-2
missing translation for 'tsca' : Yes
Recommended Storage : Keep cold
- Nitrosonium tetrafluoroborate
Signal Word
- Pericolo
Hazard Category
- Lesione oculare grave/irritazione oculare Categoria 1
- Corrosione/irritazione della pelle Categoria 1B
Hazard Statement
- H314-Provoca gravi ustioni cutanee e gravi lesioni oculari.
- H318-Provoca gravi lesioni oculari.
- EUH031-A contatto con acidi libera gas tossici.
Precautionary Statement
- P280-Indossare guanti/indumenti protettivi/Proteggere gli occhi/il viso.
- P301+P330+P331-IN CASO DI INGESTIONE: sciacquare la bocca. NON provocare il vomito.
- P305+P351+P338-IN CASO DI CONTATTO CON GLI OCCHI: sciacquare accuratamente per parecchi minuti. Togliere le eventuali lenti a contatto se è agevole farlo. Continuare a sciacquare.
- P310-Contattare immediatamente un CENTRO ANTIVELENI/un medico .
Supplemental information
- MIXTURE LIST-Contiene: Nitrosonium tetrafluoroborate
RUO – Research Use Only
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