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Nitrosonium tetrafluoroborate, 98%, Thermo Scientific Chemicals
Descrizione
Nitrosonium tetrafluoroborate is a nitrosating agent and oxidizer used in organic synthesis. It is also used to convert arylamines directly to diazonium tetrafluoroborates, which undergo the Balz-Schiemann reaction in situ to give high yields of aryl fluorides. Further, it is used as a catalyst for iodination of aromatics by iodide ion with air as oxidant, conversion of secondary amines to nitrosamines and in deamination of primary amides. It is involved in the conversion of arylhydrazines to azides. In addition to this, it reacts with ferrocene to prepare ferrocenium tetrafluoroborate.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Nitrosonium tetrafluoroborate is a nitrosating agent and oxidizer used in organic synthesis. It is also used to convert arylamines directly to diazonium tetrafluoroborates, which undergo the Balz-Schiemann reaction in situ to give high yields of aryl fluorides. Further, it is used as a catalyst for iodination of aromatics by iodide ion with air as oxidant, conversion of secondary amines to nitrosamines and in deamination of primary amides. It is involved in the conversion of arylhydrazines to azides. In addition to this, it reacts with ferrocene to prepare ferrocenium tetrafluoroborate.
Solubility
Soluble in acetonitrile.
Notes
Hygroscopic. Air and moisture sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with acids and amines.
Specifica
Specifica
| Punti di ebollizione | 250°C (0.01 mmHg)(Sublimation) |
| Materiale o nome chimico | Nitrosonium tetrafluoroborate |
| Punto di fusione | 250°C (Sublimation) |
| Quantità | 2 g |
| Numero UN | UN3260 |
| Indice di Merck | 14,6649 |
| Informazioni di solubilità | Soluble in acetonitrile. |
| Peso formulazione | 116.82 |
| Percent Purity | 98% |
| Odore | Irritating |
| Vedi altri risultati |
Sicurezza e movimentazione
- Nitrosonium tetrafluoroborate
- Pericolo
- Lesione oculare grave/irritazione oculare Categoria 1
- Corrosione/irritazione della pelle Categoria 1B
- H314-Provoca gravi ustioni cutanee e gravi lesioni oculari.
- H318-Provoca gravi lesioni oculari.
- EUH031-A contatto con acidi libera gas tossici.
- P280-Indossare guanti/indumenti protettivi/Proteggere gli occhi/il viso.
- P301+P330+P331-IN CASO DI INGESTIONE: sciacquare la bocca. NON provocare il vomito.
- P305+P351+P338-IN CASO DI CONTATTO CON GLI OCCHI: sciacquare accuratamente per parecchi minuti. Togliere le eventuali lenti a contatto se è agevole farlo. Continuare a sciacquare.
- P310-Contattare immediatamente un CENTRO ANTIVELENI/un medico .
- MIXTURE LIST-Contiene: Nitrosonium tetrafluoroborate
RUO – Research Use Only
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