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Nickel(II) chloride hexahydrate, 98%, Thermo Scientific Chemicals
Descrizione
Nickel(II) chloride is used in electroplating and as a catalyst for organic conversions, for example in chemo-selective thioacetalization of aldehydes. In combination with lithium aluminum hydride, it serves as a reducing agent for alkenes, alkynes, and organic halides; it can cleave N-O bond and open epoxides. It is used to prepare a wide array of complexes since water ligands can be easily replaced by amines, thioether, ammonia, and thiolates. It is a precursor to several nickel-phosphine complexes, such as bis(triphenylphosphine)nickel(II) chloride, which are used in alkyne trimerizations, carbonylations, and as catalysts in organic reactions such as Suzuki-Miyaura cross coupling reactions as an alternative to palladium(0) catalysts. It is the precursor to acetylacetonate complex of Ni, used for producing 1,5-cyclooctadiene complex, an important reagent in organonickel chemistry. It can be used to prepare the sandwich compound nickelocene through dimethoxyethane complex of nickel chloride.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Nickel(II) chloride is used in electroplating and as a catalyst for organic conversions, for example in chemo-selective thioacetalization of aldehydes. In combination with lithium aluminum hydride, it serves as a reducing agent for alkenes, alkynes, and organic halides; it can cleave N-O bond and open epoxides. It is used to prepare a wide array of complexes since water ligands can be easily replaced by amines, thioether, ammonia, and thiolates. It is a precursor to several nickel-phosphine complexes, such as bis(triphenylphosphine)nickel(II) chloride, which are used in alkyne trimerizations, carbonylations, and as catalysts in organic reactions such as Suzuki-Miyaura cross coupling reactions as an alternative to palladium(0) catalysts. It is the precursor to acetylacetonate complex of Ni, used for producing 1,5-cyclooctadiene complex, an important reagent in organonickel chemistry. It can be used to prepare the sandwich compound nickelocene through dimethoxyethane complex of nickel chloride.
Notes
Store away from incompatible substances such as peroxides, strong acids and potassium.

Specifica
Specifica
Materiale o nome chimico | Nickel(II) chloride hexahydrate |
Punto di fusione | 140°C (in 2H2O) |
pH | 4.9 |
Quantità | 1000 g |
Formula lineare | NiCl2·6H2O |
Numero UN | UN3288 |
Indice di Merck | 14,6505 |
Informazioni di solubilità | Freely soluble in water. Soluble in ethylene glycol,ethanol,and ammonium hydroxide. |
Peso formulazione | 237.71 (129.60 Anhydrous) |
Percent Purity | 98% |
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- Nickel(II) chloride hexahydrate
- Pericolo
- Tossicità acuta Categoria 3
- Sensibilizzante delle vie respiratorie Categoria 1
- Mutagenicità di cellule germinali Categoria 2
- cancerogenicità Categoria 1A
- Tossicità per la riproduzione Categoria 1B
- Tossicità specifica per organi bersaglio (esposizione ripetuta) Categoria 1
- PERICOLO A LUNGO TERMINE PER L'AMBIENTE ACQUATICO Cronico 1
- Corrosione/irritazione della pelle Categoria 2
- Sensibilizzazione della pelle Categoria 1
- PERICOLO ACUTO PER L'AMBIENTE ACQUATICO Acuto 1
- H301-Tossico se ingerito.
- H331-Tossico se inalato.
- H315-Provoca irritazione cutanea.
- H334-Può provocare sintomi allergici o asmatici o difficoltà respiratorie se inalato.
- H317-Può provocare una reazione allergica cutanea.
- H341-Sospettato di provocare alterazioni genetiche.
- H350i-Può provocare il cancro se inalato.
- H360D-Può nuocere al feto.
- H372-Provoca danni agli organi.
- H410-Molto tossico per gli organismi acquatici con effetti di lunga durata.
- P273-Non disperdere nell'ambiente.
- P201-Procurarsi istruzioni specifiche prima dell'uso.
- P308+P311-In caso di esposizione o di possibile esposizione: contattare un CENTRO ANTIVELENI/un medico/.
- P501b-Smaltire il prodotto/recipiente in conformità con le disposizioni locali/regionali/nazionali/internazionali.
RUO – Research Use Only
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