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  5. Lithium diisopropylamide, 2M sol. in THF/n-heptane/ethylbenzene, AcroSeal™

Lithium diisopropylamide, 2M sol. in THF/n-heptane/ethylbenzene, AcroSeal™

CAS: 4111-54-0 | C6H14LiN | 107.125 g/mol

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Chemische Identifikatoren

CAS 4111-54-0, 142-82-5, 109-99-9, 100-41-4, 108-18-9
Formula molecolare C6H14LiN
Molecular Weight (g/mol) 107.125
Numero MDL MFCD00064449
InChI Key ZCSHNCUQKCANBX-UHFFFAOYSA-N
Sinonimo lithium diisopropylamide, unii-ol028kiw1i, lithium di-isopropylamide, lithium diisopropyl amide, 2-propanamine, n-1-methylethyl-, lithium salt, ol028kiw1i, lithium di propan-2-yl azanide, 2-propanamine, n-1-methylethyl-, lithium salt 1:1, lithium n,n-diisopropylamide, ipr2nli
PubChem CID 2724682
IUPAC Name lithium;di(propan-2-yl)azanide
SMILES [Li+].CC(C)[N-]C(C)C
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10174680
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Thermo Scientific Acros
268831000 		100 mL Flacone in vetro AcroSeal™
69.75€
100mL
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10511691
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Thermo Scientific Acros
268838000 		800 mL AcroSeal™ Glass Bottle
257.00€
800mL
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Beschreibung

Beschreibung

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Spezifikation

Chemische Identifikatoren

4111-54-0, 142-82-5, 109-99-9, 100-41-4, 108-18-9
107.125
ZCSHNCUQKCANBX-UHFFFAOYSA-N
2724682
[Li+].CC(C)[N-]C(C)C
C6H14LiN
MFCD00064449
lithium diisopropylamide, unii-ol028kiw1i, lithium di-isopropylamide, lithium diisopropyl amide, 2-propanamine, n-1-methylethyl-, lithium salt, ol028kiw1i, lithium di propan-2-yl azanide, 2-propanamine, n-1-methylethyl-, lithium salt 1:1, lithium n,n-diisopropylamide, ipr2nli
lithium;di(propan-2-yl)azanide

Spezifikation

Lithium diisopropylamide
2M Solution in THF/n-Heptane
60.0°C to 136.0°C
MFCD00064449
Lithium diisopropylamide: 26.0% (2.0M)
0.8100g/mL
lithium diisopropylamide, unii-ol028kiw1i, lithium di-isopropylamide, lithium diisopropyl amide, 2-propanamine, n-1-methylethyl-, lithium salt, ol028kiw1i, lithium di propan-2-yl azanide, 2-propanamine, n-1-methylethyl-, lithium salt 1:1, lithium n,n-diisopropylamide, ipr2nli
ZCSHNCUQKCANBX-UHFFFAOYSA-N
lithium;di(propan-2-yl)azanide
2724682
24.6 to 30.0% (Lithium diisopropylamide)
2°C
Brown-Red or Orange to Yellow
4111-54-0, 142-82-5, 109-99-9, 100-41-4, 108-18-9
C6H14LiN
Solvent: THF 59%, n-Heptane: 28%, Ethylbenzene: 13%
02,49; 03,184; 04,298; 05,400; 06,334; 07,204; 08,292; 09,280; 10,241; 11,296; 12,277; 14,193; 15,188; 16,15; 17,165
15, 3215
Solubility in water: decomposes. Other solubilities: soluble in thf, n-heptane, ethylbenzene, miscible with liquid aliphatic and aromatic, hydrocarbons, ethers and tertiary amines
[Li+].CC(C)[N-]C(C)C
107.125
107.12
0.81
Soluzione
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Sicherheit und Handhabung

Sicherheit und Handhabung

GHS P Statement May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Causes severe skin burns and eye damage. May cause respiratory irritation. Highly flammable liquid and vapor. Toxic to aquatic life with long lasting effects. Reacts violently with water. May form explosive peroxides. Suspected of causing cancer.

GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

Danger

missing translation for 'einecsNumber' : 223-893-0

missing translation for 'tsca' : TSCA

Recommended Storage : Keep the solution at < 10°C at which it is stable

Produktidentifikator
  • Lithium diisopropylamide, 2M solution in THF/n-heptane/ethylbenzene

Signalwort
  • Pericolo

Gefahrenkategorie
  • Tossicità acuta Categoria 4
  • PERICOLO A LUNGO TERMINE PER L'AMBIENTE ACQUATICO Cronico 2
  • Tossicità in caso di aspirazione Categoria 1
  • cancerogenicità Categoria 2
  • Lesione oculare grave/irritazione oculare Categoria 1
  • Liquido infiammabile Categoria 2
  • Corrosione/irritazione della pelle Categoria 1B
  • Tossicità specifica per organi bersaglio (esposizione ripetuta) Categoria 2
  • Tossicità specifica per organi bersaglio (esposizione singola) Categoria 3

Gefahrenhinweis
  • H304-Può essere letale in caso di ingestione e di penetrazione nelle vie respiratorie.
  • H318-Provoca gravi lesioni oculari.
  • H314-Provoca gravi ustioni cutanee e gravi lesioni oculari.
  • H351-Sospettato di provocare il cancro.
  • H373-Può provocare danni agli organi.
  • H411-Tossico per gli organismi acquatici con effetti di lunga durata.
  • H335-Può irritare le vie respiratorie.
  • H336-Può provocare sonnolenza o vertigini.
  • H302-Nocivo se ingerito.
  • H225-Liquido e vapori facilmente infiammabili.
  • EUH014-Reagisce violentemente con l'acqua.
  • EUH019-Può formare perossidi esplosivi.

Sicherheitshinweis
  • P210-Tenere lontano da fonti di calore, superfici riscaldate, scintille, fiamme e altre fonti di innesco. Vietato fumare.
  • P280-Indossare guanti/indumenti protettivi/Proteggere gli occhi/il viso.
  • P301+P330+P331-IN CASO DI INGESTIONE: sciacquare la bocca. NON provocare il vomito.
  • P303+P361+P353-IN CASO DI CONTATTO CON LA PELLE (o con i capelli): togliere immediatamente tutti gli indumenti contaminati. Sciacquare la pelle/fare una doccia.
  • P305+P351+P338-IN CASO DI CONTATTO CON GLI OCCHI: sciacquare accuratamente per parecchi minuti. Togliere le eventuali lenti a contatto se è agevole farlo. Continuare a sciacquare.
  • P310-Contattare immediatamente un CENTRO ANTIVELENI/un medico .

Sicherheitsdatenblatt (SDS)
Dokumentation

Dokumentation

Zertifikate

RUO – Research Use Only

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