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  8. Dess-Martin periodinane, Thermo Scientific Chemicals

Dess-Martin periodinane, Thermo Scientific Chemicals

Codice prodotto. 11362777
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Quantità:
1 g
5 g
25 g
Les retours ne sont pas autorisés pour ce produit. Consulta la politica di reso
Les retours ne sont pas autorisés pour ce produit. Consulta la politica di reso

Descrizione

Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

Solubility
Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.

Notes
Store in cool place. Air and moisture sensitive. Incompatible with strong reducing agents, combustible material and water.
TRUSTED_SUSTAINABILITY

Identificatori chimici

CAS 87413-09-0
Formula molecolare C13H13IO8
Molecular Weight (g/mol) 424.14
Numero MDL MFCD00130127
InChI Key NKLCNNUWBJBICK-UHFFFAOYSA-N
PubChem CID 159087
SMILES CC(=O)O[I]1(OC(C)=O)(OC(C)=O)OC(=O)C2=CC=CC=C12

Specifica

Materiale o nome chimico Dess-Martin periodinane
Punto di fusione 130°C to 132°C (decomposition)
Quantità 1 g
Numero UN UN1479
Beilstein 4548207
Sensibilità Air, light, and moisture sensitive
Indice di Merck 14,2933
Sinonimo dess-martin periodinane, triacetoxyperiodinane, 1,1,1-triacetoxy-1,1-dihydro-1,2-benziodoxol-3 1h-one, dess-martin reagent, dess-martinperiodinane, dess-martin, dess martin periodinane, dess martin, dess-martin periodane
Informazioni di solubilità Soluble in chloroform,acetone,acetonitrile and methylene chloride. Slightly soluble in ether and hexane.
IUPAC Name (1,1-diacetyloxy-3-oxo-1$l^{5},2-benziodoxol-1-yl) acetate
Peso formulazione 424.15
Percent Purity ≥95%
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RUO – Research Use Only

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