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1-Methoxy-2-methyl-1-(trimethylsiloxy)propene, 97%, Thermo Scientific Chemicals

CAS: 31469-15-5 | C8H18O2Si | 174.32 g/mol

64.22€ - 242.21€

Identificatori chimici

CAS 31469-15-5
Formula molecolare C8H18O2Si
Molecular Weight (g/mol) 174.32
Numero MDL MFCD00010232
InChI Key JNOGVQJEBGEKMG-UHFFFAOYSA-N
Sinonimo 1-methoxy-2-methyl-1-trimethylsiloxy propene, methyl trimethylsilyl dimethylketene acetal, dimethylketene methyl trimethylsilyl acetal, 1-methoxy-2-methylprop-1-en-1-yl oxy trimethylsilane, silane, 1-methoxy-2-methyl-1-propenyl oxy trimethyl, 1-methoxy-1-trimethylsiloxy-2-methyl-1-propene, dimethylketene methyltrimethylsilylacetal, 1-methoxy-1-trimethylsilyloxy-2-methylpropene, 1-methoxy-2-methyl-1-propenyloxy trimethylsilane, 1-methoxy-2-methylprop-1-enoxy-trimethylsilane
PubChem CID 552336
IUPAC Name (1-methoxy-2-methylprop-1-enoxy)-trimethylsilane
SMILES COC(O[Si](C)(C)C)=C(C)C
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Prodotti 2
Codice del prodotto Marca Quantità Prezzo Quantità e disponibilità  
Codice del prodotto Marca Quantità Prezzo Quantità e disponibilità  
11337056
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Thermo Scientific Alfa Aesar
L06931.06
5 g
64.22€
5g
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11347056
SDS Vedere i documenti
Thermo Scientific Alfa Aesar
L06931.14
25 g
242.21€
25g
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Descrizione

Descrizione

1-Methoxy-2-methyl-1-(trimethylsiloxy)propene is used in the synthesis of chiral β-lactams by reacting with (S)-alkylidene(1-arylethyl)amines in the presence of titanium tetrachloride. It acts as a catalyst or initiator in the group-transfer polymerization. It is also used as a versatile reagent in conjugate addition4 and aldol reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-Methoxy-2-methyl-1-(trimethylsiloxy)propene is used in the synthesis of chiral β-lactams by reacting with (S)-alkylidene(1-arylethyl)amines in the presence of titanium tetrachloride. It acts as a catalyst or initiator in the group-transfer polymerization. It is also used as a versatile reagent in conjugate addition4 and aldol reactions.

Solubility
Hydrolyzes in water.

Notes
Moisture Sensitive. Incompatible materials are Strong oxidizing agents and Strong acids. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Specifica

Identificatori chimici

31469-15-5
174.32
JNOGVQJEBGEKMG-UHFFFAOYSA-N
552336
COC(O[Si](C)(C)C)=C(C)C
C8H18O2Si
MFCD00010232
1-methoxy-2-methyl-1-trimethylsiloxy propene, methyl trimethylsilyl dimethylketene acetal, dimethylketene methyl trimethylsilyl acetal, 1-methoxy-2-methylprop-1-en-1-yl oxy trimethylsilane, silane, 1-methoxy-2-methyl-1-propenyl oxy trimethyl, 1-methoxy-1-trimethylsiloxy-2-methyl-1-propene, dimethylketene methyltrimethylsilylacetal, 1-methoxy-1-trimethylsilyloxy-2-methylpropene, 1-methoxy-2-methyl-1-propenyloxy trimethylsilane, 1-methoxy-2-methylprop-1-enoxy-trimethylsilane
(1-methoxy-2-methylprop-1-enoxy)-trimethylsilane

Specifica

35°C to 36°C (15mmHg)
31469-15-5
MFCD00010232
1362893
1-methoxy-2-methyl-1-trimethylsiloxy propene, methyl trimethylsilyl dimethylketene acetal, dimethylketene methyl trimethylsilyl acetal, 1-methoxy-2-methylprop-1-en-1-yl oxy trimethylsilane, silane, 1-methoxy-2-methyl-1-propenyl oxy trimethyl, 1-methoxy-1-trimethylsiloxy-2-methyl-1-propene, dimethylketene methyltrimethylsilylacetal, 1-methoxy-1-trimethylsilyloxy-2-methylpropene, 1-methoxy-2-methyl-1-propenyloxy trimethylsilane, 1-methoxy-2-methylprop-1-enoxy-trimethylsilane
JNOGVQJEBGEKMG-UHFFFAOYSA-N
(1-methoxy-2-methylprop-1-enoxy)-trimethylsilane
552336
97%
Moisture sensitive
1-Methoxy-2-methyl-1-(trimethylsiloxy)propene
C8H18O2Si
UN1993
30°C (86°F)
Hydrolyzes in water.
COC(O[Si](C)(C)C)=C(C)C
174.32
174.32
1.415
0.858
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Sicurezza e movimentazione

Sicurezza e movimentazione

GHS H Statement
H226-H315-H319-H335
Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c

H226-H315-H319-H335

missing translation for 'dotInformation' : Transport Hazard Class: 3; Packing Group: III; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.

missing translation for 'einecsNumber' : 000-000-0

missing translation for 'tsca' : No

Recommended Storage : Ambient temperatures

SDS
Documenti

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RUO – Research Use Only

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